By Eduardo J. Bottani, Juan M.D. Tascón
This e-book covers the main major points of adsorption by means of carbons, trying to fill the prevailing hole among the fields of adsorption and carbonaceous fabrics. either easy and utilized elements are offered. the 1st element of the ebook introduces actual adsorption and carbonaceous fabrics, and is by way of a piece about the basics of adsorption by way of carbons. This ends up in improvement of a sequence of theoretical techniques that function an creation to the subsequent part within which adsorption is especially envisaged as a device to signify the porous texture and floor chemistry of carbons. specific awareness is paid to a couple novel nanocarbons, and the electrochemistry of adsorption by means of carbons can also be addressed. eventually, numerous very important technological purposes of fuel and liquid adsorption by way of carbons in components akin to environmental security and effort garage represent the final element of the ebook.
- the 1st e-book to handle the interaction among carbonaceous fabrics and adsorption
- contains vital environmental functions, akin to the elimination of unstable natural compounds from polluted atmospheres
- covers either gas-solid and liquid-solid adsorption
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Additional info for Adsorption by Carbons
Sing, and J. Weitkamp, eds). Wiley/VCH, pp. 1828–63. 14. E. Molecular modeling of adsorption from the gas phase. In Handbook of Porous Solids (F. W. Sing, and J. Weitkamp, eds). Wiley/VCH, pp. 182–236. 15. W. (1994). Physisorption of gases by carbon blacks. Carbon, 32, 1311–7. 16. Badalyan, A. and Pendleton, P. (2003). Analysis of uncertainties in manometric gas adsorption measurements. Langmuir, 19, 7919–28. 17. B. (1947). Heats of adsorption on carbon black. J. Am. Chem. , 69, 95–101. 18. M. D.
P. (2001). Reference data for the adsorption of methanol on carbon materials. Carbon, 39, 193–200. 27. P. (2001). Reference data for the adsorption of dichloromethane on carbon materials. Carbon, 39, 465–72. 28. M. W. (1989). Multilayer adsorption of nitrogen and alkanes by non-porous carbons and silicas. Pure Appl. , 61, 1836–40. 14 Chapter 1 Overview of Physical Adsorption by Carbons 29. B. and Quirke, N. (2001). Characterization of porous materials by gas adsorption: comparison of nitrogen at 77 K and carbon dioxide at 298 K on activated carbon.
A characteristic value of r is obtained from the slope of the FHH plot. In the case of nitrogen adsorption at 77 K on nonporous carbons and silicas, the derived values of r are generally remarkably constant (r = 2 70), which confirms the almost “universal” character of the nitrogen multilayer . Linear FHH multilayer plots are also given by other adsorptives such as butane, neopentane, methanol, dichloromethane, and benzene, but the corresponding values of r appear to be somewhat more variable [11, 25–28].